[N,N-Bis(2,6-diisopropylphenyl)pent-2-ene-2,4-diiminato(1−)]bis(1,2,4-diazaphosphol-1-yl)aluminium(III)
نویسندگان
چکیده
In the title compound, [Al(C(29)H(41)N(2))(C(2)H(2)N(2)P)(2)], the Al(III) atom is coordinated by four N atoms from β-diketiminate and 1,2,4-diaza-phospho-lide ligands in a slightly distorted tetra-hedral fashion.
منابع مشابه
[N,N′-Bis(2,6-diisopropylphenyl)methanimidamidato][η8-1,4-bis(trimethylsilyl)cyclooctatetraenyl](tetrahydrofuran)samarium(III) toluene monosolvate
The title compound, [Sm(C(25)H(35)N(2))(C(14)H(24)Si(2))(C(4)H(8)O)]·C(7)H(8), was prepared by treatment of anhydrous samarium trichloride with a 1:1 mixture of in situ-prepared Li(DippForm) [DippFormH = N,N'-bis-(2,6-diisopropyl-phen-yl)methanimidamide] and Li(2)(COT'') [COT'' = 1,4-bis-(trimethyl-sil-yl)cyclo-octa-tetra-enyl] in tetra-hydro-furan (THF). Despite the presence of two very bulky ...
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In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra-hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy-ethane mol-ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2)...
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In the title compound, [Co(NCSe)(2)(C(9)H(7)N(7))(2)(H(2)O)(2)], the Co(2+) cation is coordinated by two seleno-cyanate anions, two 2,6-bis-(4H-1,2,4-triazol-4-yl)pyridine ligands and two water mol-ecules within a slightly distorted N(4)O(2) octa-hedron. The asymmetric unit consists of one Co(2+) cation, which is located on a center of inversion, as well as one seleno-cyanate anion, one 2,6-bis...
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In the structures of the 2,6-bis-(1,2,4-triazoly-3-yl)methyl-substituted pyridine compound, C11H11N7, (I) and the iodide triiodide salt, C13H17N7 (2+)·I(-)·I3 (-), (II), the dihedral angles between the two triazole rings and the pyridine ring are 66.4 (1) and 74.6 (1)° in (I), and 68.4 (2)° in (II), in which the dication lies across a crystallographic mirror plane. The overall packing structure...
متن کاملA monoclinic polymorph of N,N′-bis(2,6-diisopropylphenyl)formamidine
A new polymorph of N,N'-bis-(2,6-diisopropyl-phen-yl)formamidine, C(25)H(36)N(2), is reported, which is different from the previously reported ortho-rhom-bic structure. The mol-ecule crystallizes in the E-anti configuration, with tautomeric disorder of the N-bonded H atoms and no clear distinction between imine and amine functionalities. The mol-ecules form hydrogen-bonded dimers with inter-mol...
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